Stratospheric Aerosols from Ci-i4 Photochemistry on Neptune
نویسندگان
چکیده
We have used a combined photochemicalcondensation model to study hydrocarbon ices produced from CH4 photolysis in the stratosphere of Neptune. We predict a total stratospheric haze production rate of 4.2 X 10-15 grams cm -2 s -1 (75% ethane, 25% acetylene, trace diacetylene). The total production rate is insensitive to within a factor of two to order of magnitude changes in the eddy diffusion coefficient and methane mixing ratio, which is within our estimate of uncertainty for this number. The condensation temperatures are 97 K for C4H2, 71 K for C2H2, and 64 K for C2H6. Voyager 2 images of Neptune will be able to confirm the presence of stratospheric aerosols and provide constraints on their production rate and location.
منابع مشابه
Methane Photochemistry and Haze Production on Neptune
A numerical model was used to study methane photochemistry in the stratosphere of Neptune. The observed mixing ratio of methane, 2%, forces photolysis to occur near the CH4 homopause. For an assumed nominal value of the eddy mixing coefficient of 106 cm 2 sec -1 at the CH4 homopause, the predicted average mixing ratios of CzH6 and C2Hz, 1.5 x 10 -6 and 6 x 10 -7, respectively, agree well with o...
متن کاملSO[subscript 2] photolysis as a source for sulfur mass- independent isotope signatures in stratospehric aerosols
Signatures of sulfur isotope mass-independent fractionation (S-MIF) have been observed in stratospheric sulfate aerosols deposited in polar ice. The S-MIF signatures are thought to be associated with stratospheric photochemistry following stratospheric volcanic eruptions, but the exact mechanism responsible for the production and preservation of these signatures is debated. In order to identify...
متن کاملSO2 photolysis as a source for sulfur mass-independent isotope signatures in stratospehric aerosols
Signatures of sulfur isotope mass-independent fractionation (S-MIF) have been observed in stratospheric sulfate aerosols deposited in polar ice. The S-MIF signatures are thought to be associated with stratospheric photochemistry following stratospheric volcanic eruptions, but the exact mechanism responsible for the production and preservation of these signatures is debated. In order to identify...
متن کاملIn situ measurements of the NO / NO ratio for testing atmospheric photochemical models
Simultaneous in situ measurements of NO 2, NO, 03, C10, pressure and temperature have been made for the first time, presenting a unique opportunity to test our current understanding of the photochemistry of the lower stratosphere. Data were collected from several flights of the ER-2 aircraft at mid-latitudes in May 1993 during NASA's Stratospheric Photochemistry, Aerosols and Dynamics Expeditio...
متن کاملHydrocarbon nucleation and aerosol formation in Neptune's atmosphere.
Photodissociation of methane at high altitude levels in Neptune's atmosphere leads to the production of complex hydrocarbon species such as acetylene (C2H2), ethane (C2H6), methylacetylene (CH3C2H), propane (C3H8), diacetylene (C4H2), and butane (C4H8). These gases diffuse to the lower stratosphere where temperatures are low enough to initiate condensation. Particle formation may not occur re...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2007